LUMINESCENCE OF CHROMIUM(3) COMPOUNDS

被引：15

作者：

HEMPEL, JC

MATSEN, FA

机构：

[1] Department of Chemistry, University of Texas, Austin

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 08期

关键词：

D O I：

10.1021/j100842a007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Crystal field energy level calculations, including spin-orbit interaction, provide a basis for the understanding of intersystem crossover in chromium(III) compounds. In particular, they provide a scheme for predicting the ratio of fluorescence to total luminescence for effectively octahedral chromium(III) systems.

引用

收藏

页码：2502 / &

相关论文

共 18 条

[1] RELAXATION OF EXCITED STATES IN CR(3) COMPLEXES [J].

CAMASSEI, FD ;

FORSTER, LS .

JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (06) :2603-&

[2] ELECTRONIC TRANSITIONS IN CHROMIUM(III) COMPLEXES .4. RADIATIVE AND NON-RADIATIVE TRANSITION PROBABILITIES [J].

CHATTERJEE, KK ;

FORSTER, LS .

SPECTROCHIMICA ACTA, 1964, 20 (10) :1603-1609

[3] ELECTRONIC TRANSITIONS IN CHROMIUM (III) COMPLEXES .3. LUMINESCENCE QUANTUM YIELDS AND LIFETIMES [J].

DEARMOND, K ;

FORSTER, LS .

SPECTROCHIMICA ACTA, 1963, 19 (10) :1687-1693

[4]

GAUSMANN G, 1968, J CHEM PHYS, V48, P4056

[5] 3 ELECTRON (OR HOLE) CUBIC LIGAND FIELD SPECTRUM [J].

LIEHR, AD .

JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (06) :1314-+

[6] SPIN-FREE QUANTUM CHEMISTRY .6. SPIN CONSERVATION [J].

MATSEN, FA ;

KLEIN, DJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (08) :2477-&

[7] SPIN-FREE QUANTUM CHEMISTRY .8. CRYSTAL FIELD PROBLEM [J].

MATSEN, FA ;

ELLZEY, ML .

JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (08) :2495-&

[8] BAND WIDTHS IN THE SPECTRA OF MANAGANOUS AND OTHER TRANSITION-METAL COMPLEXES [J].

ORGEL, LE .

JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (10) :1824-1826

[9]

PORTER GB, 1963, Z PHYSIK CHEM FRANKF, V37, P109

[10] UBER DIE TEMPERATURABHANGIGKEIT DER 2EG-]4A2G-PHOSPHORESZENZ GLASARTIG ERSTARRTER LOSUNGEN VON CHROM(3)-KOMPLEXEN [J].

SCHLAFER, HL ;

GAUSMANN, H ;

WITZKE, H .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1967, 56 (1-2) :55-&