ION-MOLECULE-EQUILIBRIA IN THE VAPORS OVER CESIUM IODIDE AND SODIUM-FLUORIDE

被引：28

作者：

SIDOROVA, IV

GUSAROV, AV

GOROKHOV, LN

机构：

[1] Institute for High Temperatures, Academy of Sciences, Moscow

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1979年 / 31卷 / 04期

关键词：

D O I：

10.1016/0020-7381(79)80073-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A mass-spectrometric study of ion-molecule equilibria in the vapor over cesium iodide has been performed. The ions Cs+, Cs2I+, Cs3I2+,I-, CsI2- and Cs2I3- were detected. The enthalpies of formation of the gaseous ions Cs2I+ and CsI2- have been determined as (kcal mol-1) ΔHf.00 (Cs2I+, g) = 36.4 ± 1.3; ΔHf.00 (CsI2-, g) = -117.7 ± 1.3. In the case of sodium fluoride no negative NaxFx+1- ions were found. MoO3F- and AlF4- ions were identified. © 1979.

引用

页码：367 / 372

页数：6

共 16 条

[1] ABSORPTION SPECTRUM OF GASEOUS F- AND ELECTRON AFFINITIES OF HALOGEN ATOMS [J].