PALLADIUM(0)-CATALYZED TRANSFER HYDROGENATION OF ALKYNES TO CIS-ALKENES WITH HCO2H-NET3

被引：43

作者：

TANI, K ^{[1
]}

ONO, N ^{[1
]}

OKAMOTO, S ^{[1
]}

SATO, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOMOLEC ENGN,MEGURO KU,TOKYO 152,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

关键词：

D O I：

10.1039/c39930000386

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transfer hydrogenation of alkynes using HCO2H-NEt3 as a hydrogen donor in the presence of Pd0-catalyst proceeds highly stereoselectively to afford cis-alkenes in excellent yields, thus providing a practical method for conversion of alkynes to cis-alkenes.

引用

页码：386 / 387

页数：2

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