INFRARED-LASER PYROLYSIS OF DIETHYLZINC - 1ST EVIDENCE FOR BETA-HYDRIDE ELIMINATION

被引：21

作者：

LINNEY, RE ^{[1
]}

RUSSELL, DK ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1993年 / 3卷 / 06期

关键词：

INFRARED LASER PYROLYSIS; PYROLYSIS; DIETHYLZINC;

D O I：

10.1039/jm9930300587

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The IR laser-powered homogeneous pyrolysis of diethylzinc has been shown to result in the deposition of zinc hydride, identified by FTIR and H-1 NMR spectroscopy, and by comparison with the chemical behaviour of an authentic sample. This observation demonstrates for the first time that the major pathway for the homogeneous pyrolysis of Et2Zn is that of beta-hydride elimination, in contrast to the bond-homolysis radical mechanism suggested in earlier conventional pyrolysis studies.

引用

页码：587 / 590

页数：4

共 25 条

[1]

Ashby E. C., 1977, INORGANIC SYNTHESES, V17, P6

[2] LASER-POWERED HOMOGENEOUS PYROLYSIS OF TRIMETHYLALUMINUM - TRAPPING OF THE DIMETHYLALUMINUM RADICAL [J].