RADICAL POLYMERIZATION IN HALOGENATED SOLVENTS .2. METHYL METHACRYLATE POLYMERIZATION INITIATED BY BENZOYL PEROXIDE

被引：28

作者：

BURNETT, GM

CAMERON, GG

PARKER, BM

机构：

[1] Department of Chemistry, University of Aberdeen, Old Aberdeen, Scotland

来源：

EUROPEAN POLYMER JOURNAL | 1969年 / 5卷 / 01期

关键词：

D O I：

10.1016/0014-3057(69)90120-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The fractional rates of polymerization of methyl methacrylate initiated by benzoyl peroxide at 60° in chloro- and bromobenzene are similar to comparable polymerizations initiated by azobisisobutyronitrile. In the case of iodobenzene, the initial rise in fractional rate with increasing solvent concentration reaches a maximum at a much lower solvent concentration. The results are discussed on the basis of the theory of Olivé and Henrici-Olivé and it is concluded that final proof of the validity of this theory is still lacking. © 1969.

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页码：231 / &

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