THE INTERFACIAL STABILITY OF LI WITH 2 NEW SOLVENT-FREE IONIC LIQUIDS - 1,2-DIMETHYL-3-PROPYLIMIDAZOLIUM IMIDE AND METHIDE

被引:202
作者
KOCH, VR [1 ]
NANJUNDIAH, C [1 ]
APPETECCHI, GB [1 ]
SCROSATI, B [1 ]
机构
[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY
关键词
D O I
10.1149/1.2044332
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The room temperature stability of the Li interface in the presence of 1,2-dimethyl-3-propylimidazolium imide and methide was followed by electrochemical impedance spectroscopy for a period of 112 days. We found that while Li foil initially reacted with both ionic liquids, the interfacial film on Li formed in the imide-based electrolyte stabilized at an interfacial resistance of 1.5 k Ohm cm(2), while that for the methide-based electrolyte rose to an interfacial resistance value exceeding 50 k Ohm cm(2).
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页码:L116 / L118
页数:3
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