OXIDATION-STATE-DEPENDENT CONFORMATION IN CP-ASTERISK-MO(DMIT)(2)(CIRCLE-MINUS) AND ANTIFERROMAGNETIC ORDERING (T-N=8 K) OF THE NEUTRAL 17-ELECTRON COMPLEX CP-ASTERISK-MO(DMIT)(2)(CIRCLE-MINUS)

被引：30

作者：

FOURMIGUE, M ^{[1
]}

COULON, C ^{[1
]}

机构：

[1] CNRS,CTR RECH PAUL PASCAL,F-33600 PESSAC,FRANCE

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 12期

关键词：

D O I：

10.1002/adma.19940061210

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal dithiolene complexes are attractive for the development of novel materials with extended electronic properties. The preparation of Cp*Mo(dmit)(2)(-) and its investigation by cyclic voltammetry, antiferromagnetic resonance, and electron paramagnetic resonance are described. Complexes of this class, i.e., with heteroatom substitution on the dmit dithiolene ligand, are shown to exhibit conformational flexibility directly related to the orbital occupancy.

引用

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页码：948 / 952

页数：5

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