HETEROGENEOUS PHOTOCHEMICAL FORMATION OF CL-ATOMS FROM NACL AEROSOL, NOX AND OZONE

被引：43

作者：

BEHNKE, W

ZETZSCH, C

机构：

[1] Fraunhofer-Institut für Toxikologie und Aerosoforschung, D-3000 Hannover 61

来源：

JOURNAL OF AEROSOL SCIENCE | 1990年 / 21卷

关键词：

SEA SPRAY AEROSOL; NACL; CL ATOMS; O3; OH; HCL; NO2CL; N2O5; PHOTOCHEMICAL SMOG;

D O I：

10.1016/0021-8502(90)90226-N

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The influence of NaCl and simulated sea spray aerosol on photochemical smog is investigated in an aerosol smog chamber experiment in teflon bags in the presence of NO(X) and ozone. Besides the expected OH, a considerable formation of atomic Cl is observed in the presence of simulated tropospheric sunlight. The photolytic precursor of the atomic Cl is identified to be NO2Cl formed in a dark reaction of N2O5 with NaCl.

引用

页码：S229 / S232

页数：4

共 18 条

[1] HETEROGENEOUS FORMATION OF CHLORINE ATOMS FROM VARIOUS AEROSOLS IN THE PRESENCE OF O-3 AND HCL [J].