DETERMINATION OF THE HALF-WAVE POTENTIAL OF THE SPECIES LIMITING THE POTENTIAL WINDOW - MEASUREMENT OF GIBBS TRANSFER ENERGIES AT THE WATER 1,2-DICHLOROETHANE INTERFACE

被引：114

作者：

SHAO, Y ^{[1
]}

STEWART, AA ^{[1
]}

GIRAULT, HH ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 16期

关键词：

D O I：

10.1039/ft9918702593

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The numerical integration of the differential equation for cyclic voltammetry has been performed for the case where the reverse potential is set prior to the forward peak potential. A working curve stemming from these integrations allows the determination of the half-wave potential of species limiting the potential window. This technique has been applied to the measurement of formal Gibbs energies of transfer of ions across the water/1,2-dichlorethane interface. The validity of the TATB (tetraphenylarsonium tetraphenylborate) assumption is also discussed.

引用

页码：2593 / 2597

页数：5

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