INFINITE DILUTION ACTIVITY-COEFFICIENTS FOR OXYGENATE SYSTEMS DETERMINED USING A DIFFERENTIAL STATIC CELL

被引:55
作者
PIVIDAL, KA [1 ]
BIRTIGH, A [1 ]
SANDLER, SI [1 ]
机构
[1] UNIV DELAWARE, DEPT CHEM ENGN, NEWARK, DE 19716 USA
关键词
D O I
10.1021/je00008a025
中图分类号
O414.1 [热力学];
学科分类号
摘要
A new differential static cell apparatus has been used to measure activity coefficients at infinite dilution for binary systems of water separately with methanol, ethanol, 2-propanol, tetrahydrofuran, and methanol in cyclohexane as a function of temperature, and at 15-degrees-C, we report all binary infinite dilution activity coefficients among methanol-MTBE-cyclopentane and water-2-propanol-ethyl acetate. A description of the apparatus and experimental procedure is given, as well as an error analysis of our experimental data.
引用
收藏
页码:484 / 487
页数:4
相关论文
共 16 条
[1]   LIMITATIONS OF DIFFERENTIAL STATIC APPARATUS IN DILUTE REGIONS [J].
ALESSI, P ;
FERMEGLIA, M ;
KIKIC, I .
FLUID PHASE EQUILIBRIA, 1988, 43 (2-3) :355-358
[2]  
ALESSI P, 1986, FLUID PHASE EQUILIBR, V29, P249
[3]  
Boublik T., 1984, VAPOUR PRESSURES PUR
[4]   ACTIVITY COEFFICIENTS AT INFINITE DILUTION [J].
GAUTREAUX, MF ;
COATES, J .
AICHE JOURNAL, 1955, 1 (04) :496-500
[5]   VAPOR-LIQUID EQUILIBRIA FROM TOTAL PRESSURE MEASUREMENTS - NEW APPARATUS [J].
GIBBS, RE ;
VANNESS, HC .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1972, 11 (03) :410-&
[6]  
GMEHLING J, 1977, DECHEMA CHEM DATA 1, V1, P39
[7]   THE DETERMINATION OF ACTIVITY COEFFICIENTS AT INFINITE DILUTION FROM GAS CHROMATOGRAPHIC MEASUREMENTS [J].
HARDY, CJ .
JOURNAL OF CHROMATOGRAPHY, 1959, 2 (05) :490-498
[8]   GENERALIZED METHOD FOR PREDICTING 2ND VIRIAL-COEFFICIENTS [J].
HAYDEN, JG ;
OCONNELL, JP .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1975, 14 (03) :209-216
[9]   THE EFFECT OF FLUID PROPERTIES ON EBULLIOMETER OPERATION [J].
KNEISL, P ;
ZONDLO, JW ;
WHITING, WB ;
BEDELL, M .
FLUID PHASE EQUILIBRIA, 1989, 46 (01) :85-94
[10]   INFINITE DILUTION ACTIVITY-COEFFICIENTS OF NORMAL-ALCOHOLS AS A FUNCTION OF DEXTRIN CONCENTRATION IN WATER DEXTRIN SYSTEMS [J].
LEBERT, A ;
RICHON, D .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1984, 32 (05) :1156-1161