COMPOSITION OF ASPHALT BASED ON GENERIC FRACTIONATION USING SOLVENT DEASPHALTENING ELUTION-ADSORPTION CHROMATOGRAPHY AND DENSIMETRIC CHARACTERIZATION

被引:439
作者
CORBETT, LW
机构
[1] Esso Research and Engineering Co., Linden, N.J. 07036
关键词
D O I
10.1021/ac60273a004
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper describes a convenient method for determining asphalt composition based on fractionation into four generic components. The method involves solvent deasphaltening for recovery of asphaltenes, followed by elution-adsorption chromatography to yield saturates, naphthene-aromatics, and polar-aromatics. The densimetric method was then applied to define the average chemical structures present. Examples are presented to show the effect of distillation and crude source, noting that molecular weight as well as chemical structure varies appreciably. This suggests that these two characteristics should be considered along with the proportion of each component when making asphalt composition analyses. © 1969, American Chemical Society. All rights reserved.
引用
收藏
页码:576 / &
相关论文
共 12 条
[1]   DENSIMETRIC METHOD FOR CHARACTERIZING ASPHALT [J].
CORBETT, LW .
ANALYTICAL CHEMISTRY, 1964, 36 (10) :1967-&
[2]  
CORBETT LW, 1967, ACS PETR DIV
[3]  
DICKIE JD, 1967, ANAL CHEM, V14, P1847
[4]  
GRANT FR, 1940, P AM ASS PET TECHNOL, V12, P87
[5]  
KLEINSCHMIDT LR, 1955, RES NBS, V54, P163
[6]   CONSTITUTION OF ASPHALTIC BITUMEN - CHARACTERIZATION OF BITUMENS BY A COMBINATION OF PYROLYSIS HYDROGENATION AND GAS-LIQUID CHROMATOGRAPHY [J].
KNOTNERU.J .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1967, 6 (01) :43-&
[7]  
MARCUSSON J, 1916, Z ANGEW CHEM, V29, P21
[8]   COMPOUNDING RUBBER WITH PETROLEUM PRODUCTS [J].
ROSTLER, FS ;
STERNBERG, HW .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1949, 41 (03) :598-608
[9]  
SCHWEYER HE, 1967, P HRB RECORD, P30