HIGH CONDUCTIVITY AND PHASE-TRANSITIONS OF TETRAMETHYLAMMONIUM HYDROXIDE PENTAHYDRATE, (CH3)4NOH.5H2O

被引：40

作者：

KURIYAMA, N

SAKAI, T

MIYAMURA, H

KATO, A

ISHIKAWA, H

机构：

[1] Government Industrial Research Institute, Osaka, AIST, MITI, Osaka, 563

来源：

SOLID STATE IONICS | 1990年 / 40-1卷

关键词：

D O I：

10.1016/0167-2738(90)90150-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A clathrate hydrate, tetramethylammonium hydroxide pentahydrate was found to be a fast "proton" or "hydroxide ion" conductor, about 5×10-3 S cm-1, for the room temperature phase (phase III). The high temperature phase (phase I) has body-centered cubic symmetry and high conductivity comparable to the liquid phase. Details of the mediate phase (phase II) are ambiguous. © 1990.

引用

页码：906 / 909

页数：4

共 7 条

[1] ROLE OF ION-EXCHANGE IN SOLID-STATE CHEMISTRY [J].