UNSATURATED ACYLGERMANES ISOMERIZE BY A CHAIN MECHANISM INVOLVING RADICAL CYCLIZATION TO THE CARBONYL GROUP OF AN ACYLGERMANE

被引：49

作者：

CURRAN, DP

LIU, HT

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 11期

关键词：

D O I：

10.1021/jo00011a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Experimental evidence indicates that unsaturated acylgermanes isomerize by a three-step chain mechanism that involves (1) addition of a germyl radical to the double bond, (2) radical cyclization to the acylgermane, and (3) fragmentation of the intermediate beta-germyl alkoxy radical.

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页码：3463 / 3465

页数：3

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