NEW C-C BOND FORMATION THROUGH THE NICKEL-CATALYZED ELECTROCHEMICAL COUPLING OF 1,3-ENYNES AND CARBON-DIOXIDE

被引：26

作者：

DERIEN, S ^{[1
]}

CLINET, JC ^{[1
]}

DUNACH, E ^{[1
]}

PERICHON, J ^{[1
]}

机构：

[1] UNIV PARIS 11,COORDINAT ORGAN LAB,CNRS,UA 255,ICMO,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 424卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83151-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of 1,3-enynes has been carboxylated in a nickel-catalysed electrochemical reaction carried out in a single-compartment cell fitted with a consumable magnesium anode. When 2,2'-bipyridine (bipy) or pentamethyldiethylene triamine (PMDTA) are added as the ancillary ligands, an overall hydrocarboxylation of the triple bond occurs through stereoselective cis-addition.

引用

页码：213 / 224

页数：12

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