ARYNE CHEMISTRY .19. SOME REACTIONS OF TETRACHLORO-4-METHOXY-PYRIDINE WITH GRIGNARD REAGENTS AND ORGANOLITHIUM COMPOUNDS

被引：15

作者：

FERNANDEZ, RA

HEANEY, H

JABLONSK.JM

MASON, KG

WARD, TJ

机构：

[1] Department of Chemistry, University of Technology, Loughborough, Leicestershire

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 14期

关键词：

D O I：

10.1039/j39690001908

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sterically non-demanding Grignard and organolithium reagents displace the methoxy-group in tetrachloro-4-methoxy-pyridine, with the formation of 4-alkyl- or 4-aryl-tetrachloropyridines. t-Butyl-lithium forms trichloro-4-methoxy-3- pyridyl-lithium, which decomposes in the presence of furan with the formation of 2,3-dichloro-5,8-dihydro-4-methoxy-5,8-epoxyquinoline.

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页码：1908 / +

页数：1

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