AN ELECTRON SPIN RESONANCE STUDY OF PHOTOLYSIS OF TETRAFLUORO-P-BENZOQUINONE

被引:14
作者
HUDSON, A
LEWIS, JW
机构
[1] Chemical Laboratory, University of Sussex
来源
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 05期
关键词
D O I
10.1039/j29690000531
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The monoprotonated tetrafluoro-p-benzosemiquinone radical has been prepared from the parent quinone by photochemicaily induced hydrogen-atom abstraction in a variety of solvents. The radical dissociates readily in hydroxylic solvents and in some cases rapid proton-transfer equilibria were observed which gave time-averaged e.s.r. spectra.
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页码:531 / &
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