ADSORPTION-KINETICS OF SURFACTANTS AT FLUID INTERFACES - EXPERIMENTAL CONDITIONS AND PRACTICE OF APPLICATION OF THEORETICAL-MODELS

被引：16

作者：

MILLER, R

机构：

[1] Academy of Sciences, the G.D.R., Central Institute of Organic Chemistry, 1199 Berlin

来源：

COLLOIDS AND SURFACES | 1990年 / 46卷 / 01期

关键词：

D O I：

10.1016/0166-6622(90)80049-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interpretation of experimental data for the adsorption kinetics of surfactants at fluid interfaces can be performed in a quantitative way for all experiments with simple boundary conditions: stationary interfaces, continuously growing drops and bubbles, and laminar flowing films. For these cases a polynomial solution derived on the basis of a collocation method can be applied. Based on an example from the literature it is shown that there is no essential need to develop any empirical models of surfactant adsorption kinetics. Equilibrium adsorption data, as well as the proof of surface chemical purity of surfactants to be investigated, are emphasized as necessary prerequisites for dynamic interfacial studies. © 1990.

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页码：75 / 83

页数：9

相关论文

共 49 条

[1] THE PROPERTIES OF FRESHLY FORMED SURFACES .18. DYNAMIC SURFACE POTENTIALS AND THE ADSORPTION PROCESS - MOLECULAR ORIENTATION IN SOLUBLE FILMS OF DECYL ALCOHOL [J].

ADDISON, CC ;

LITHERLAND, D .

JOURNAL OF THE CHEMICAL SOCIETY, 1953, (APR) :1143-1150

[2] THE PROPERTIES OF FRESHLY FORMED SURFACES .15. THE APPLICATION OF THE CONTRACTING LIQUID-JET TECHNIQUE TO THE MEASUREMENT OF TENSIONS AT LIQUID LIQUID INTERFACES [J].

ADDISON, CC ;

ELLIOTT, TA .

JOURNAL OF THE CHEMICAL SOCIETY, 1950, (NOV) :3090-3096

[3] THE PROPERTIES OF FRESHLY FORMED SURFACES .13. THE COMPRESSIBILITY OF SOLUBLE FILMS OF DECYL AND OTHER ALCOHOLS [J].

ADDISON, CC ;

HUTCHINSON, SK .

JOURNAL OF THE CHEMICAL SOCIETY, 1949, (DEC) :3404-3406

[4] THE PROPERTIES OF FRESHLY FORMED SURFACES .12. AN EXPERIMENTAL STUDY OF THE DESORPTION PROCESS WITH PARTICULAR REFERENCE TO AQUEOUS DECYL ALCOHOL SOLUTIONS [J].

ADDISON, CC ;

HUTCHINSON, SK .

JOURNAL OF THE CHEMICAL SOCIETY, 1949, (DEC) :3395-3403

[5] THE PROPERTIES OF FRESHLY-FORMED SURFACES .8. EXPANSION OF SOLUBLE FILMS OF DECOIC ACID AT THE AIR-WATER INTERFACE [J].

ADDISON, CC ;

BAGOT, J ;

MCCAULEY, HS .

JOURNAL OF THE CHEMICAL SOCIETY, 1948, (JUL) :936-942

[6] THE PROPERTIES OF FRESHLY-FORMED SURFACES .7. THE APPLICATION OF THE VERTICAL-PLATE TECHNIQUE TO THE STUDY OF SOLUBLE FILMS AT AIR-LIQUID AND LIQUID-LIQUID INTERFACES [J].

ADDISON, CC ;

HUTCHINSON, SK .

JOURNAL OF THE CHEMICAL SOCIETY, 1948, (JUL) :930-936

[7] The properties of freshly formed surfaces Part II The rate of adsorption of isoAmyl alcohol at the air-water surface [J].

Addison, CC .

JOURNAL OF THE CHEMICAL SOCIETY, 1944, :252-256

[8] THE PROPERTIES OF FRESHLY FORMED SURFACES .11. FACTORS INFLUENCING SURFACE ACTIVITY AND ADSORPTION RATES IN AQUEOUS DECYL ALCOHOL SOLUTIONS [J].

ADDISON, CC ;

HUTCHINSON, SK .

JOURNAL OF THE CHEMICAL SOCIETY, 1949, (DEC) :3387-3395

[9] The surface ageing of solutions. [J].

Alexander, AE .

TRANSACTIONS OF THE FARADAY SOCIETY, 1941, 37 :0015-0024

[10]

BARTHOLOME E, 1950, MELLIAND TEXTILBER, V31, P487

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