[(TRIPHOS)CO(DELTA-P3)CR2(CO)10] - TRINUCLEAR HETEROMETAL COMPLEX CONTAINING CYCLO-TRIPHOSPHORUS AS MU-LIGAND

被引：18

作者：

MIDOLLINI, S ^{[1
]}

ORLANDINI, A ^{[1
]}

SACCONI, L ^{[1
]}

机构：

[1] UNIV FLORENCE,CNR LAB,IST CHIM GEN & INORGAN,I-50132 FLORENCE,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 01期

关键词：

D O I：

10.1002/anie.197900811

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The P atoms of the P3 ring in the complex (triphos)Co(δ‐P3) still possess donor properties. Hence the complex can react with Cr(CO)6 in the molar ratio 1:1 or 1:2 to give a di‐or trinuclear complex 1. The original “donor complex” with a CoP6 skeleton remains almost unchanged on bonding to the Cr(Co)5 groups. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：81 / 82

页数：2

共 3 条

[1] CYCLO-TRIPHOSPHORUS (DELTA-P3) AS A LIGAND IN COBALT AND NICKEL-COMPLEXES WITH 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE - FORMATION AND STRUCTURES [J].

DIVAIRA, M ;

GHILARDI, CA ;

MIDOLLINI, S ;

SACCONI, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) :2550-2551

[2]

Dobson G. R., 1966, ADV INORG CHEM RAD, V8, P1

[3] CRYSTAL AND MOLECULAR-STRUCTURES OF PENTACARBONYLTRIPHENYLPHOSPHINECHROMIUM(O) AND PENTACARBONYL(TRIPHENYL PHOSPHITE)CHROMIUM(O) [J].

PLASTAS, HJ ;

STEWART, JM ;

GRIM, SO .

INORGANIC CHEMISTRY, 1973, 12 (02) :265-272

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