REACTIONS OF ETA-2-13-ACYLTETRACARBONYLMANGANESE COMPLEXES DERIVED FROM PODOCARPIC ACID WITH ALKENES - CYCLOPENTAANNULATION OF RING-C

被引：25

作者：

CAMBIE, RC ^{[1
]}

METZLER, MR ^{[1
]}

RICKARD, CEF ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 426卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83046-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of 13-acyltetracarbonylmanganese(I) complexes derived from podocarpic acid (1) have been coupled with alkenes to give steroidal analogues. 8H-Cyclopent[b]phenanthrene derivatives were isolated from reaction of a 12-acetyltetracarbonylmanganese complex. A study has been made of activation of the manganese complexes towards coupling reactions by transpalladation, by oxidative decarbonylation at room temperature, and by thermal promotion. The stereochemistry of two of the cyclopentaannulated adducts has been established by X-ray crystallography.

引用

页码：213 / 245

页数：33

共 24 条

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