THE REACTION OF TRIS(TRIMETHYLSILYL)SILANE WITH ACID-CHLORIDES

被引：35

作者：

BALLESTRI, M

CHATGILIALOGLU, C

CARDI, N

SOMMAZZI, A

机构：

[1] CNR,LCOCEA,VIA CHIM 8,I-40064 OZZANO EMILIA,ITALY

[2] IST GUIDO DONEGANI SPA,I-28100 NOVARA,ITALY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(00)91733-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction.

引用

页码：1787 / 1790

页数：4

共 24 条

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