THE EFFECT OF ELECTROLYTES ON BUBBLE COALESCENCE IN WATER

被引:456
作者
CRAIG, VSJ
NINHAM, BW
PASHLEY, RM
机构
[1] AUSTRALIAN NATL UNIV,DEPT CHEM,POB 4,CANBERRA,ACT 2601,AUSTRALIA
[2] AUSTRALIAN NATL UNIV,DEPT APPL MATH,CANBERRA,ACT 2601,AUSTRALIA
关键词
D O I
10.1021/j100141a047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of common electrolytes were found either to reduce the rate of bubble coalescence in water or to have no effect. For a range of cations and anions, a system of combining rules emerges that characterizes the behavior of all the salts studied. The specific effects of electrolytes on bubble coalescence may be related to their effect on water structure and hence the hydrophobic interaction. The phenomenon may have applications in various fields, including decompression sickness, hydrophobic chromatography, and possibly evolution.
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页码:10192 / 10197
页数:6
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