A CYCLOADDITION CYCLODEHYDROGENATION ROUTE FROM STILBENOIDS TO EXTENDED AROMATIC-HYDROCARBONS

被引：68

作者：

MULLER, M ^{[1
]}

MAUERMANNDULL, H ^{[1
]}

WAGNER, M ^{[1
]}

ENKELMANN, V ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 15期

关键词：

CYCLOADDITIONS; CYCLODEHYDROGENATIONS; DIELS-ALDER REACTIONS; GRAPHITIC SECTIONS; POLYCYCLES;

D O I：

10.1002/anie.199515831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unconventional route to planar graphitic fragments has been demonstrated with the novel synthesis of aromatic polycycles such as 2. The intramolecular Diels–Alder reaction of 1 is followed by aromatization and oxidative aryl–aryl coupling to afford 2 (C30H16) in high yield. The analogous synthesis of a C54H22 polyarene shows that this approach can be used to prepare larger graphitic sections. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1583 / 1586

页数：4

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