INFLUENCE OF LIGAND ENVIRONMENT ON THE PROTONATION REACTIONS OF HYDRAZIDO(2-) COMPLEXES OF MOLYBDENUM AND TUNGSTEN - X-RAY STRUCTURES OF[M(8-QUIN)(NNH2)(PME2PH)3]I(M=MO OR W - 8-QUIN=QUINOLIN-8-OLATE)

被引：13

作者：

CHATT, J ^{[1
]}

FAKLEY, ME ^{[1
]}

RICHARDS, RL ^{[1
]}

机构：

[1] ROTHAMSTED EXPTL STN,DEPT MOLEC STRUCT,HARPENDEN AL5 2JQ,HERTFORDSHIRE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 170卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)83197-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [MX2(NNH2)(PMe2Ph)3] (M = Mo or W; X = Cl, Br or I) give ammonia with H2SO4/MeOH, the yield depending upon X. Ammonia is also obtained from [Mo(8-quin)(NNH2)(PMe2Ph)3]I (M = Mo, 8-quin = quinolin-8-olate) but the tungsten analogue gives hydrazine only. Crystal structures of the 8-quin molybdenum and tungsten complexes are reported. © 1979.

引用

页码：C6 / C8

页数：3

共 4 条

[1] RECENT ADVANCES IN CHEMISTRY OF NITROGEN-FIXATION
CHATT, J
DILWORTH, JR
RICHARDS, RL
[J]. CHEMICAL REVIEWS, 1978, 78 (06) : 589 - 625
[2] CONVERSION OF DINITROGEN IN ITS MOLYBDENUM AND TUNGSTEN COMPLEXES INTO AMMONIA AND POSSIBLE RELEVANCE TO NITROGENASE REACTION
CHATT, J
PEARMAN, AJ
RICHARDS, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (19): : 1852 - 1860
[3] HYDRAZIDO(2-)-COMPLEXES OF MOLYBDENUM AND TUNGSTEN FORMED FROM DINITROGEN COMPLEXES BY PROTONATION AND LIGAND-EXCHANGE
CHATT, J
RICHARDS, RL
PEARMAN, AJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (12): : 1766 - 1776
[4] PREPARATION AND PROPERTIES OF MOLYBDENUM AND TUNGSTEN DINITROGEN COMPLEXES .9. CONVERSION OF LIGATING DINITROGEN INTO HYDRAZINE
HIDAI, M
MIZOBE, Y
TAKAHASHI, T
UCHIDA, Y
[J]. CHEMISTRY LETTERS, 1978, (10) : 1187 - 1188

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