A NOVEL TYPE OF HYDRIDE-TRANSFER PHOTOCATALYSIS BY RU-II-PYRIDINE COMPLEXES - REGIOCONTROLLED REDUCTION OF AN NAD(P) MODEL-COMPOUND BY TRIETHYLAMINE

被引：25

作者：

ISHITANI, O

INOUE, N

KOIKE, K

IBUSUKI, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 04期

关键词：

D O I：

10.1039/c39940000367

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ru(trpy)(bpy)(py)]2(+) (trpy = 2,2' :6',2''-terpyridine, bpy = 2,2'-bipyridine, py = pyridine) and [Ru(LL)(2)(py)(2)](2+) (LL = a bidentate ligand) photocatalysed the regiocontrolled reduction of 1-benzyl-4-carbamoyle-pyridinium cation to the dihydro form with no formation of the half-reduced dimers, the photocatalysis proceeds through the photosubstitution of a py ligand of the Ru complexes and the subsequent photoformation of [Ru(trpy)(bpy)H](+) or [Ru(LL)(2)(py)H](+).

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页码：367 / 368

页数：2

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