STRUCTURE OF BIS(2,2'-BIPYRIDYL)(SACCHARINATO-N)COPPER(II) SACCHARINATE DIHYDRATE

被引：53

作者：

HERGOLDBRUNDIC, A

GRUPCE, O

JOVANOVSKI, G

机构：

[1] FAC SCI CYRIL, INST CHEM, CYRIL, CROATIA

[2] METHODIUS UNIV, SKOPJE, CROATIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1991年 / 47卷 / 12期

关键词：

Bipyridyl - Cu atoms - Dihydrates - Distorted trigonal bipyramid - Independent reflections - Saccharinate - Water molecule;

D O I：

10.1107/S0108270191006558

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Cu(C7H4NO3S)(C10H8N2)2][C7H4NO3S].-2H2O, M(r) = 776.30, orthorhombic, C222(1), a = 26.300 (6), b = 15.596 (2), c = 16.936 (4) angstrom, V = 6947 (2) angstrom 3, Z = 8, D(m) (by flotation) = 1.51, D(x) = 1.485 Mg m-3, lambda(Cu K-alpha) = 1.54178 angstrom, mu = 2.48 mm-1, F(000) = 3192, room temperature, final R = 0.063 for 2999 independent reflections with I > 4-sigma(I). The structure is built up of [Cu(C7H4NO3S)(C10H8N2)2]+ cations, saccharinate anions and water molecules. The Cu atom is surrounded by five N atoms in a distorted trigonal bipyramid with Cu-N distances ranging from 1.982 (5) to 2.098 (5) angstrom.

引用

页码：2659 / 2660

页数：2

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