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ROTATIONAL ANALYSIS OF THE O0(0) BAND OF THE A3E-X3A2 SYSTEM OF METHYLNITRENE
被引:16
作者:
BRAZIER, CR
CARRICK, PG
BERNATH, PF
机构:
[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA
[2] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721
关键词:
D O I:
10.1063/1.462113
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The optical emission spectrum of the methylnitrene radical has been observed at a resolution of 0.07 cm-1. Transitions to subbands with K up to 3 in the X approximately 3A2 ground state were observed and a full rotational analysis carried out. Comparison of the structural information with the highest level theoretical calculations shows agreement to within the estimated error.
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页码:919 / 926
页数:8
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