ROTATIONAL ANALYSIS OF THE O0(0) BAND OF THE A3E-X3A2 SYSTEM OF METHYLNITRENE

被引:16
作者
BRAZIER, CR
CARRICK, PG
BERNATH, PF
机构
[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA
[2] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721
关键词
D O I
10.1063/1.462113
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The optical emission spectrum of the methylnitrene radical has been observed at a resolution of 0.07 cm-1. Transitions to subbands with K up to 3 in the X approximately 3A2 ground state were observed and a full rotational analysis carried out. Comparison of the structural information with the highest level theoretical calculations shows agreement to within the estimated error.
引用
收藏
页码:919 / 926
页数:8
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