SYNTHESIS AND CARBONYLATION OF [PD(ME)(OME)((S,S)-BDPP)] [(S,S)-BDPP = (2S,4S)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE]

被引：38

作者：

TOTH, I

ELSEVIER, CJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 06期

关键词：

D O I：

10.1039/c39930000529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of [Pd(Me)(OMe){(S,S)-bdpp}] 2 by NaOMe metathesis with [Pd(Me)(Cl){(S,S)-bdpp}] 1 is reported along with the low temperature carbonylation of 2; the elimination of methyl acetate from the new carbonylation product [Pd(Me)(CO2Me){(S,S)-bdpp}] 3 proceeds readily even at -50-degrees-C.

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页码：529 / 531

页数：3

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