The Velocities of Adsorption of Hydrogen and Deuterium on Hydrogenation Catalysts

被引:23
作者
Pace, James [1 ]
Taylor, Hugh S. [1 ]
机构
[1] Princeton Univ, Frick Chem Lab, Princeton, NJ 08544 USA
关键词
D O I
10.1063/1.1749536
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The velocities of adsorption of hydrogen and deuterium have been measured on the hydrogenating oxide catalysts, chromium oxide and zinc-oxide-chromium oxide and on a supported nickel catalyst. The velocities of adsorption of the two gases are identical, within the experimental error, over a range of temperature on each surface. The fundamental importance of these observations in the theory of activated adsorption and in chemical kinetics generally is emphasized.
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页数:3
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