ASYMMETRIC DIELS-ALDER REACTIONS CHIRAL N-METHACRYLOYLSULTAMS WITH 1,3-DIENES

被引：16

作者：

OPPOLZER, W

SELETSKY, BM

BERNARDINELLI, G

机构：

[1] Département de Chimie Organique, Université de Genève

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)73222-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

R(2)AlCl-coordinated N-methacryloylsultam Ic undergoes efficient, endo-selective and highly diastereoface controlled [4+2]-additions to cyclopentadiene, isoprene, (E)-piperylene and the 2-silyloxydienes 10 and 12. The resulting crystalline cycloadducts are smoothly reduced with LiAlH4 providing the recovered auxiliary and the corresponding enantiomerically pure alcohols.

引用

页码：3509 / 3512

页数：4

共 29 条

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