INTER-MOLECULAR EXCHANGE OF SUBSTITUENTS VIA IONS (ION-PAIRS) IN CYCLOPENTADIENYL-TRIMETHYLSTANNANE AND CYCLONONATETRAENYL-TRIMETHYLSTANNANE

被引：8

作者：

BOCHE, G

HEIDENHAIN, F

STAUDIGL, B

机构：

[1] Institut für Organische Chemie der Universität, München, D-8000

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1002/anie.197902181

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formation of ion pair by solvation is invoked to explain the 1H‐NMR spectral result obtained for 1 and the analogous cyclonatetraene derivative. Thus 1 is capable of not only intramolecular exchange [1′⇄1] but also intermolecular exchange of substituents (e.g in HMPT as doner solventDo). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：218 / 219

页数：2

共 22 条

[1] MECHANISM OF ELECTROPHILIC SUBSTITUTION WITH PARTICIPATION OF ION-PAIRS IN ORGANOMETALLIC CHEMISTRY (SE2 ION-PAIR MECHANISM) [J].