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POLYENE CYCLIZATIONS USING MERCURY(II) TRIFLATE N,N-DIMETHYLANILINE COMPLEX - PARTICIPATION BY INTERNAL NUCLEOPHILES

被引：23
作者：
GOPALAN, AS
PRIETO, R
MUELLER, B
PETERS, D
机构：
[1] Department of Chemistry, New Mexico State University, Las Cruces
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 13期
关键词：
POLYENE CYCLIZATIONS; MERCURIC ION; INTERNAL NUCLEOPHILIC TERMINATION;
D O I：
10.1016/S0040-4039(00)91704-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The cyclization of a number of functionalized polyenes with mercuric triflate - N,N-dimethylaniline complex (Nishizawa's reagent) to give bicyclic or tricyclic products has been studied. Suitably positioned internal nucleophiles, such as carbonyl, hydroxy and beta-ketoester groups were found to participate to varying extent, in the termination of these cyclizations.
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页码：1679 / 1682
页数：4
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