THE NATURE OF THE 7-NORBORNYL CATION AND ITS REARRANGEMENT INTO THE 2-NORBORNYL CATION

被引：40

作者：

SIEBER, S

SCHLEYER, PV

VANCIK, H

MESIC, M

SUNKO, DE

机构：

[1] UNIV ERLANGEN NURNBERG,INST ORGAN CHEM,HENKESTR 42,D-91054 ERLANGEN,GERMANY

[2] UNIV ZAGREB,FAC NAT SCI & MATH,ORGAN CHEM LAB,41000 ZAGREB,CROATIA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct observation of the 7‐norbornyl cation was achieved for the first time by spectroscopy in an SbF5 matrix at low temperatures. Ab initio calculations at the highest level and the comparison of calculated and experimental IR spectra suggest that the unsymmetrically bridged structure 1 is the most probable for this cation. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1604 / 1606

页数：3

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