REACTIVITY OF CYCLOPALLADATED COMPOUNDS .27. METAL-INDUCED 1,5-HYDROGEN AND 1,4-HYDROGEN SHIFTS IN POLYSUBSTITUTED BUTADIENYL UNITS ETA-3-BONDED TO PALLADIUM

被引：46

作者：

SUTTER, JP

PFEFFER, M

DECIAN, A

FISCHER, J

机构：

[1] UNIV STRASBOURG 1,CHIM COORDINAT LAB,CNRS,URA 416,4 RUE BLAISE PASCAL,F-67070 STRASBOURG,FRANCE

[2] UNIV STRASBOURG 1,CRISTALLOCHIM & CHIM STRUCT LAB,CNRS,URA 424,F-67070 STRASBOURG,FRANCE

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1021/om00037a063

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3-Hexyne (2 equiv) is readily inserted into the Pd-C bond of the cyclopalladated compound derived from the ((dimethylamino)methyl)ferrocene ligand, affording a kinetic isomer, 2. The latter may be isomerized into a thermodynamic isomer 3 in pyridine at 100-degrees-C. Two further isomers of 2 are produced in refluxing pyridine and with maleic anhydride in refluxing toluene. The former is the result of a 1,4-H shift of the CH2 group gamma to the palladium atom on the butadienyl chain whereas the latter is obtained via a 1,5-H shift of the CH2 unit delta to the palladium.

引用

收藏

页码：386 / 392

页数：7

相关论文

共 29 条

[1] INSERTIONS OF DIPHENYLACETYLENE INTO CYCLOPALLADATED COMPOUNDS - CRYSTAL-STRUCTURE OF [PD((PHC=CPH)2C6H4CH2N=CH(2,6-C6H3CL2))BR] [J].

ALBERT, J ;

GRANELL, J ;

SALES, J ;

SOLANS, X .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 379 (1-2) :177-185

[2] REACTIVITY OF CYCLOPALLADATED COMPLEXES .5. INSERTION REACTIONS OF DIPHENYLACETYLENE, 1-PHENYLPROP-1-YNE, AND HEXAFLUOROBUT-2-YNE WITH CYCLOPALLADATED COMPOUNDS - CRYSTAL AND MOLECULAR-STRUCTURE OF CHLORO-(3-4-ETA-4-[(2-DIMETHYLAMINOMETHYL)PHENYL]-1,4-DIMETHYL-2,3-DIPHENYL-BUTA-1,3-DIENYL-C1N)PALLADIUM(II) AND BROMO(3-4-ETA-4-[(2-DIMETHYL-AMINOMETHYL)PHENYL]-2,4-DIMETHYL-1,3-DIPHENYLBUTA-1,3-DIENYL-C1N)-PALLADIUM(II), [J].

BAHSOUN, A ;

DEHAND, J ;

PFEFFER, M ;

ZINSIUS, M ;

BOUAOUD, SE ;

LEBORGNE, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (04) :547-556

[3]

BEYDOUN N, IN PRESS J ORGANOMET

[4] MOLECULAR-STRUCTURE OF ETA-5-[PD(CH2=CH=CMECH2CH2CH=CME2)-(MECN)](BF4), A CATIONIC PI ALLYLPALLADIUM COMPLEX WITH AN ALMOST INPLANE INTRAMOLECULAR OLEFIN COORDINATION [J].

CIAJOLO, R ;

JAMA, MA ;

TUZI, A ;

VITAGLIANO, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 295 (02) :233-238

[5]

Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV

[6] REACTIVITY OF CYCLOPALLADATED COMPOUNDS .18. COMPARED REACTIVITY OF THE PD-C BONDS OF 2 CLOSELY RELATED 6-MEMBERED PALLADOCYCLIC RINGS WITH SUBSTITUTED ALKYNES - X-RAY AND MOLECULAR-STRUCTURES OF [PD(C(PH)=C(R)C(PH)=C(R)(O-C6H4N=CMENHPH))CL] (R=CO2ET) AND [PD(C(R)[C(CO2ME)C(R)=C(R)C(R)=C(R)][O-C6H4N=CME(OH)])CL] (R=CO2ME)A [J].

DUPONT, J ;

PFEFFER, M ;

DARAN, JC ;

GOUTERON, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (09) :2421-2429

[7] ISOLATION OF A BIS(ETA-4-ARENE)DIPALLADIUM(I) COMPLEX DURING THE ANNELATION OF PALLADATED ARYL GROUPS WITH DIPHENYLACETYLENE [J].

DUPONT, J ;

PFEFFER, M ;

ROTTEVEEL, MA ;

DECIAN, A ;

FISCHER, J .

ORGANOMETALLICS, 1989, 8 (04) :1116-1118

[8] ORGANOMETALLIC CONFORMATIONAL EQUILIBRIA .10. STERIC FACTORS AND THEIR MECHANISTIC IMPLICATIONS IN PI-ALLYL(AMINE)CHLOROPALLADIUM(II) COMPLEXES [J].

FALLER, JW ;

THOMSEN, ME ;

MATTINA, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (11) :2642-&

[9]

Frenz B.A, 1978, COMPUTING CRYSTALLOG, P64

[10] TRANSITION METAL-CARBON BONDS .40. PALLADIUM(II) COMPLEXES OF [(DIMETHYLAMINO)METHYL]FERROCENE [J].

GAUNT, JC ;

SHAW, BL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 102 (04) :511-516