REGIOSELECTIVE AMINATION OF POLYUNSATURATED ETHERS

被引：7

作者：

CERICHELLI, G

FREDDI, A

LORETO, MA

PELLACANI, L

TARDELLA, PA

机构：

[1] Centro di Studio sui Meccanismi di Reazione, CNR, Dipartimento di Chimica, I-00185 Roma

[2] Dipartimento di Chimica, Università La Sapienza, I-00185 Roma

来源：

TETRAHEDRON | 1992年 / 48卷 / 12期

关键词：

NITRENE ADDITION; AZIRIDINES; CARBAMATES;

D O I：

10.1016/S0040-4020(01)88768-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Ethoxycarbonyl)nitrene (NCO2Et) adds selectively to methyl neryl ether, geranyl methyl ether, and allyl neryl ether. For all the substrates the main product (up to 50%) is the aziridine deriving from addition to the double bond remote from the oxygen atom. Competition experiments point to a different reactivity of the two kind of double bonds and these results are compared with those reported for similar substrates in other addition reactions.

引用

页码：2495 / 2500

页数：6

共 27 条

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