REGIOSELECTIVE AMINATION OF POLYUNSATURATED ETHERS

被引:7
作者
CERICHELLI, G
FREDDI, A
LORETO, MA
PELLACANI, L
TARDELLA, PA
机构
[1] Centro di Studio sui Meccanismi di Reazione, CNR, Dipartimento di Chimica, I-00185 Roma
[2] Dipartimento di Chimica, Università La Sapienza, I-00185 Roma
关键词
NITRENE ADDITION; AZIRIDINES; CARBAMATES;
D O I
10.1016/S0040-4020(01)88768-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
(Ethoxycarbonyl)nitrene (NCO2Et) adds selectively to methyl neryl ether, geranyl methyl ether, and allyl neryl ether. For all the substrates the main product (up to 50%) is the aziridine deriving from addition to the double bond remote from the oxygen atom. Competition experiments point to a different reactivity of the two kind of double bonds and these results are compared with those reported for similar substrates in other addition reactions.
引用
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页码:2495 / 2500
页数:6
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