NOVEL PHOTOACTIVATABLE NONLINEAR OPTICAL POLYMERS - POLY[((4-AZIDOPHENYL)CARBOXY)ETHYL METHACRYLATE]

被引：38

作者：

HAYASHI, A ^{[1
]}

GOTO, Y ^{[1
]}

NAKAYAMA, M ^{[1
]}

SATO, H ^{[1
]}

WATANABE, T ^{[1
]}

MIYATA, S ^{[1
]}

机构：

[1] TOKYO UNIV AGR & TECHNOL, FAC TECHNOL, DEPT MAT SYST ENGN, KOGANEI, TOKYO 184, JAPAN

来源：

MACROMOLECULES | 1992年 / 25卷 / 19期

关键词：

D O I：

10.1021/ma00045a041

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A methacrylate polymer carrying azidobenzoate groups was prepared, and its nonlinear optical properties were studied. It was found that poly[(4-azidophenyl)carboxy)ethyl methacrylate] film irradiated by UV light under an electric field showed larger second harmonic generation (SHG) than one without irradiation. This is the first photoactivatable nonlinear optical polymer. The increase of SHG by irradiation was explained by the increase of the beta-value because a photoreaction changes the azido groups to amino and azo groups.

引用

页码：5094 / 5098

页数：5

共 15 条

[1] NOVEL 2ND-ORDER NONLINEAR OPTICAL POLYMERS VIA CHEMICAL CROSS-LINKING-INDUCED VITRIFICATION UNDER ELECTRIC-FIELD
EICH, M
RECK, B
YOON, DY
WILLSON, CG
BJORKLUND, GC
[J]. JOURNAL OF APPLIED PHYSICS, 1989, 66 (07) : 3241 - 3247
[2] Poled Polymeric Nonlinear Optical Materials. Enhanced Second Harmonic Generation Stability of Cross-Linkable Matrix/Chromophore Ensembles
Hubbard, Michael A.
Marks, Tobin J.
Yang, Jian
Wong, George K.
[J]. CHEMISTRY OF MATERIALS, 1989, 1 (02) : 167 - 169
[3] MAKER FRINGES - A DETAILED COMPARISON OF THEORY AND EXPERIMENT FOR ISOTROPIC AND UNIAXIAL CRYSTALS
JERPHAGNON, J
KURTZ, SK
[J]. JOURNAL OF APPLIED PHYSICS, 1970, 41 (04) : 1667 - +
[4] OPTICAL NONLINEAR SUSCEPTIBILITIES - ACCURATE RELATIVE VALUES FOR QUARTZ, AMMONIUM DIHYDROGEN PHOSPHATE, AND POTASSIUM DIHYDROGEN PHISPHATE
JERPHAGNON, J
KURTZ, SK
[J]. PHYSICAL REVIEW B-SOLID STATE, 1970, 1 (04): : 1739 - +
[5] HIGHLY EFFICIENT AND STABLE NONLINEAR OPTICAL POLYMERS VIA CHEMICAL CROSS-LINKING UNDER ELECTRIC-FIELD
JUNGBAUER, D
RECK, B
TWIEG, R
YOON, DY
WILLSON, CG
SWALEN, JD
[J]. APPLIED PHYSICS LETTERS, 1990, 56 (26) : 2610 - 2612
[6] MANDAL BK, 1991, MAKROMOL CHEM-RAPID, V12, P63
[7] 2ND-HARMONIC GENERATION AND ABSORPTION STUDIES OF POLYMER DYE FILMS ORIENTED BY CORONA-ONSET POLING AT ELEVATED-TEMPERATURES
MORTAZAVI, MA
KNOESEN, A
KOWEL, ST
HIGGINS, BG
DIENES, A
[J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1989, 6 (04) : 733 - 741
[8] CHROMOPHORE-FUNCTIONALIZED POLYMERIC THIN-FILM NONLINEAR OPTICAL-MATERIALS - EFFECTS OF IN SITU CROSS-LINKING ON 2ND HARMONIC-GENERATION TEMPORAL CHARACTERISTICS
PARK, J
MARKS, TJ
YANG, J
WONG, GK
[J]. CHEMISTRY OF MATERIALS, 1990, 2 (03) : 229 - 231
[9] P,P'-AZOXY- AND P,P'-AZO-DIBENZOIC ACIDS
REID, EB
PRITCHETT, EG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1953, 18 (06) : 715 - 719
[10] PHOTOLYSIS OF AROMATIC AZIDES .3. QUANTUM YIELD AND MECHANISM
REISER, A
MARLEY, R
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (547P): : 1806 - &

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