GROWTH AND PERFECTION OF ORGANIC NONLINEAR-OPTICAL MATERIALS - KINETICS AND MECHANISM OF THE GROWTH OF N-(4-NITROPHENYL)PROLINOL (NPP) CRYSTALS FROM METHANOL AND TOLUENE SOLUTION

被引：31

作者：

SHEKUNOV, BY ^{[1
]}

SHEPHERD, EEA ^{[1
]}

SHERWOOD, JN ^{[1
]}

SIMPSON, GS ^{[1
]}

机构：

[1] UNIV STRATHCLYDE, DEPT PURE & APPL CHEM, GLASGOW G1 1XL, LANARK, SCOTLAND

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 18期

关键词：

D O I：

10.1021/j100018a054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Organic nonlinear optical materials are difficult to prepare in single-crystalline form due to the inhibition of growth by the solvent. This yields poor growth characteristics which result in the development oi. strain and inclusions in the grown crystal. A study has been made of the growth mechanism and morphology of N-(4-nitrophenyl)prolinol using both a polar and nonpolar solvent. The results are used to define conditions for the preparation of large crystals up to 2 x 0.8 x 0.8 cm(3) of exceptionally high optical and structural perfection.

引用

页码：7130 / 7136

页数：7