NUCLEATION AND GROWTH OF MAGNESIOFERRITE IN MGO CONTAINING O.9 PERCENT FE3+

被引:21
作者
WOODS, KN
FINE, ME
机构
[1] Materials Science Department, Northwestern University, Evanston, Illinois
关键词
D O I
10.1111/j.1151-2916.1969.tb13362.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The initial stage of precipitation of magnesioferrite from a supersaturated solid solution of 0.9 cation % Fe3+ in MgO at 500 °C was studied by fitting the magnetization curves to 7000 Oe at low temperatures with the Brillouin function. The averase umber of Fe3+ ions in a precipitate particle, increased monotonically with aging time from 9 in the as‐quenched condition to 88 after 16 h. The average spin quantum number per Fe3+ ion decreased to near its final value at an aging time corresponding to = 50. Thus the volume fraction of precipitate is near the final value when the average particle size is only about three unit cells of magnesioferrite. Copyright © 1969, Wiley Blackwell. All rights reserved
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页码:186 / &
相关论文
共 13 条
[1]  
ASIMOW RM, 1965, T METALL SOC AIME, V233, P401
[2]   MAGNETIC INTERACTIONS OF SUPERPARAMAGNETIC PARTICLES [J].
BROWN, WF .
JOURNAL OF APPLIED PHYSICS, 1967, 38 (03) :1017-&
[3]   SOME PROPERTIES OF QUENCHED MAGNESIUM FERRITES [J].
EPSTEIN, DJ ;
FRACKIEWICZ, B .
JOURNAL OF APPLIED PHYSICS, 1958, 29 (03) :376-377
[4]   VERSATILE AND SENSITIVE VIBRATING-SAMPLE MAGNETOMETER [J].
FONER, S .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1959, 30 (07) :548-557
[5]   SOLID SOLUTION + PRECIPITATION HARDENING IN MG-FE-O ALLOYS [J].
GROVES, GW ;
FINE, ME .
JOURNAL OF APPLIED PHYSICS, 1964, 35 (12) :3587-&
[6]  
KOCH FB, 1967, THESIS NORTHWESTERN
[7]   PARAMAGNETIC RESONANCE AND OPTICAL SPECTRA OF DIVALENT IRON IN CUBIC FIELDS .2. EXPERIMENTAL RESULTS [J].
LOW, W ;
WEGER, M .
PHYSICAL REVIEW, 1960, 118 (05) :1130-1136
[8]   THE PARAMAGNETIC RESONANCE SPECTRUM OF FE3+ IN THE CUBIC FIELD OF MGO [J].
LOW, W .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON SECTION B, 1956, 69 (11) :1169-1170
[9]  
Morrish A.H, 1965, PHYS PRINCIPLES MAGN, P71
[10]   SUPERPARAMAGNETIC MAGNESIOFERRITE PRECIPITATES FROM DILUTE SOLUTIONS OF IRON IN MGO [J].
WIRTZ, GP ;
FINE, ME .
JOURNAL OF APPLIED PHYSICS, 1967, 38 (09) :3729-&