SYNTHESIS AND CHARACTERIZATION OF THE NOVEL COMPLEX MU-(ETA(2),ETA(2)-DIBENZYLIDENEACETONE)FE-2(CO)(8)

被引：11

作者：

CANO, AC

ZUNIGAVILLARREAL, N

ALVAREZ, C

TOSCANO, RA

CERVANTES, M

DAZ, A

RUDLER, H

机构：

[1] Univ Nacl Autonoma Mexico, INST QUIM, MEXICO CITY 04510, DF, MEXICO

[2] LAB CHIM ORGAN PARIS, URA 408, F-75252 PARIS 05, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 01期

关键词：

IRON; CARBONYL; VINYL; KETENE; KETONE;

D O I：

10.1016/0022-328X(94)87026-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal reaction of Fe-2(CO)(9) with dibenzylideneacetone in boiling diethyl ether gives the dinuclear yellow-orange air-stable mu-(eta(2),eta(2)-dibenzylideneacetone)Fe-2(CO)(8) (I). The structure of the complex was determined by IR,H-1 NMR, and C-13 NMR spectroscopy, and X-ray crystallography.

引用

收藏

页码：C23 / C24

页数：2

相关论文

共 14 条

[1] PREPARATION OF TRICARBONYL(ETA-4-VINYLKETENE)IRON(0) COMPLEXES FROM TRICARBONYL(ETA-4-VINYL KETONE)IRON(0) COMPLEXES AND THEIR SUBSEQUENT CONVERSION TO TRICARBONYL(ETA-4-VINYLKETENIMINE)IRON(0) COMPLEXES [J].

ALCOCK, NW ;

RICHARDS, CJ ;

THOMAS, SE .

ORGANOMETALLICS, 1991, 10 (01) :231-238

[2]

ALVAREZTOLEDANO C, B SOC CHIM FR

[3]

BRADIE AM, 1972, J CHEM SOC DA, P2031

[4] REACTIONS OF COORDINATED LIGANDS .13. RING-OPENING OF 2,3-BIS-(HYDROXYMETHYL)METHYLENECYCLOPROPANE WITH NONACARBONYLDI-IRON - MOLECULAR AND CRYSTAL-STRUCTURES OF TRICARBONYL-ETA4-[3-METHYLENE-ENDO-4-VINYLDIHYDROFURAN-2(3H)-ONE]IRON(O] AND TETRACARBONYL-ETA2-[3-METHYL-ENE-EXO-4-VINYLDIHYDROFURAN-2(3H)-ONE]IRON(0)Y [J].

CHISNALL, BM ;

GREEN, M ;

HUGHES, RP ;

WELCH, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (19) :1899-1907

[5] REACTIVITY OF DIIRON NONACARBONYL IN TETRAHYDROFURAN .3. NEW IRON CARBONYL COMPLEX OF ACENAPHTHYLENE, (C12H8)FE(CO)4 [J].

COTTON, FA ;

LAHUERTA, P .

INORGANIC CHEMISTRY, 1975, 14 (01) :116-122

[6]

DEEMING JA, 1982, COMPREHENSIVE ORGANO, V4, P387

[7] REACTIONS OF COORDINATED LIGANDS .14. REGIOSPECIFIC THERMAL REARRANGEMENTS OF TETRACARBONYL-ETA2-[3-METHYLENE-EXO-4-VINYLDIHYDRO-FURAN-2(3H)-ONE]IRON(0) AND TRICARBONYL-ETA4-[3-METHYLENE-ENDO-4-VINYL-DIHYDROFURAN-2(3H)-ONE]IRON(0) COMPLEXES - MECHANISMS OF METAL-PROMOTED 1,3-HYDROGEN SHIFTS [J].

GREEN, M ;

HUGHES, RP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (19) :1907-1914

[8] SYNTHESIS AND REACTIONS OF TETRACARBONYLIRON AND TRICARBONYLIRON COMPLEXES OF ALPHA,BETA-UNSATURATED KETONES [J].

HOWELL, JAS ;

JOSTY, PL ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 39 (02) :329-&

[9] STRUCTURES OF TETRACARBONYL(2-3-ETA-MALEIC ACID)IRON, CIS-[FE(C4H4O4)(CO)4](1) AND TETRACARBONYL(2-3-ETA-FUMARIC ACID)IRON, TRANS-[FE(C4H4O4)(CO)4](2) [J].

HSIOU, Y ;

WANG, Y ;

LIU, LK .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :721-724

[10] MOLECULAR AND CRYSTAL STRUCTURE OF 1,5-CYCLOOCTADIENE-BIS(IRON TETRACARBONYL) [J].

KRUGER, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 22 (03) :697-&