1,3-DIPOLAR CYCLOADDITION OF N-METHYLAZOMETHINE YLIDE TO C-7O

被引：86

作者：

WILSON, SR

LU, Q

机构：

[1] Department of Chemistry, New York University, Washington Square, New York

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 20期

关键词：

D O I：

10.1021/jo00125a040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,3-Dipolar cycloaddition of N-methylazomethine ylide to C-70 affords a mixture of three isomeric monoadducts la-c. The isomers were separated and appear to result from addition to 6,6-ring fusions of C-70 at the 1,9-, 7,8-, and 22,23-bonds. Competition experiments indicate that C-60 is slightly more than twice as reactive as C-70 toward this reaction.

引用

页码：6496 / 6498

页数：3

共 34 条

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