ENERGY DEPENDENCE OF ION-MOLECULE REACTIONS .2. METHYL CHLORIDE

被引：21

作者：

MCASKILL, NA

机构：

[1] School of Chemistry, University of New South Wales, Kensington, NSW, 2033

[2] Department of Chemistry, University of Toronto, Toronto 181, ON

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 11期

关键词：

D O I：

10.1071/CH9692275

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ion-molecule reactions of ions in methyl chloride were studied in the gas phase at source pressures of up to 120 μ in a mass spectrometer using ions having exit energies which ranged from 0.2 to 2.0 eV. The ions produced by secondary processes included CH4Cl+, CH2Cl+, and C2H6Cl+. The rate constant for the reaction of CH3Cl+ was found to be independent of the ion energy in the energy range studied. A theoretical rate constant which is independent of the ion energy was also derived for reactions between ions and polar molecules. Negative ion spectra were briefly examined. © 1969, CSIRO. All rights reserved.

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页码：2275 / &

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