COBALT(2) COMPLEXES OF 2,3,5,6-TETRAKIS(2-PYRIDYL)PYRAZINE AND 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE

被引:21
作者
GOODWIN, HA
SYLVA, RN
VAGG, RS
WATTON, EC
机构
[1] School of Chemistry, University of New South Wales, Kensington, NSW, 2033
[2] School of Chemistry, Macquarie University, North Ryde, NSW
关键词
D O I
10.1071/CH9691605
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bis-ligand cobalt(II) complexes of 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,3,5,6.tetrakis(2-pyridyl)pyrazine have been prepared. The conductivities of the complexes in nitromethane solution correspond to values expected for bi-unielectrolytes. The temperature dependence of their magnetism has shown that in some instances there exists a spin-state equilibrium in the metal atom while in others the metal atom is spin-free and Curie-Weiss laws are obeyed. © 1969, CSIRO. All rights reserved.
引用
收藏
页码:1605 / &
相关论文
共 16 条