QUANTUM RESONANCE STRUCTURE IN THE 3-DIMENSIONAL F+H2 REACTION

被引：146

作者：

REDMON, MJ ^{[1
]}

WYATT, RE ^{[1
]}

机构：

[1] UNIV TEXAS,AUSTIN,TX 78712

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 63卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)87001-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Evidence for a quantum resonance in the three-dimensional F + H2 (v = 0, i = 0) → FH(v = 2, all i) + H reaction is presented. Relative to the collinear reaction, this resonance is much broader and is shifted by about 0.1 eV to higher energies. This resonance has not been predicted in previous quasiclassical trajectory computations, or in approximate quantum calculations. © 1979.

引用

页码：209 / 212

页数：4

共 18 条

[1] F+H2, D2, HD REACTIONS - CHEMICAL LASER DETERMINATION OF PRODUCT VIBRATIONAL-STATE POPULATIONS AND F+HD INTRAMOLECULAR KINETIC ISOTOPE-EFFECT
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[2] F+H2 (NU=0)-]FH (NU'LESS-THAN-OR-EQUAL-TO3)+H REACTION - QUANTUM COLLINEAR REACTION PROBABILITIES ON 3 DIFFERENT POTENTIAL-ENERGY SURFACES
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[10] MUCKERMAN JT, COMMUNICATION

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