POLYMERIZATION MODES OF TETRACYANOQUINODIMETHANE AND VINYLOXY COMPOUNDS

被引：26

作者：

IWATSUKI, S

ITOH, T

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Nagoya 464, Furo-cho, Chikusa-ku

来源：

MACROMOLECULES | 1979年 / 12卷 / 02期

关键词：

D O I：

10.1021/ma60068a008

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymerization of tetracyanoquinodimethane (TCNQ) with n-butyl vinyl ether, isobutyl vinyl ether, 2-chloroethyl vinyl ether, phenyl vinyl ether, and vinyl acetate was studied in acetonitrile. The first two vinyl ethers homopolymerize in the presence of TCNQ and the last three compounds copolymerize in an alternating fashion with TCNQ. The two polymerization modes were correlated to electron-donating character of the monomers by Taft's substituent constants for vinyloxy compounds. © 1979, American Chemical Society. All rights reserved.

引用

页码：208 / 212

页数：5

共 23 条

[1] RELATIVE REACTIVITIES IN VINYL COPOLYMERIZATION [J].

ALFREY, T ;

PRICE, CC .

JOURNAL OF POLYMER SCIENCE, 1947, 2 (01) :101-106

[2] POLYMERIZATION OF ALKYL VINYL ETHERS CATALYZED BY TETRACYANOQUINODIMETHAN [J].

AOKI, S ;

STILLE, JK .

MACROMOLECULES, 1970, 3 (04) :473-&

[3] POLYMERIZATION OF ALKYL VINYL ETHERS BY TRICYANOETHENOL IN TETRACYANOETHYLENE [J].

AOKI, S ;

TARVIN, RF ;

STILLE, JK .

MACROMOLECULES, 1970, 3 (04) :472-&

[4] ESTIMATION OF HAMMETT SUBSTITUENT CONSTANTS [J].

CHARTON, M .

JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (11) :3121-&

[5]

Foster R., 1969, ORGANIC CHARGE TRANS, P387

[6] STRUCTURE AND REACTIVITY OF ALPHA,BETA-UNSATURATED ETHERS .4. EFFECTS OF RING SUBSTITUENTS ON ACID-CATALYZED HYDROLYSIS RATE OF PHENYL VINYL ETHER [J].

FUENO, T ;

MATSUMURA, I ;

OKUYAMA, T ;

FURUKAWA, J .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1968, 41 (04) :818-+

[7] The effect of structure upon the reactions of organic compounds benzene derivatives [J].

Hammett, LP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1937, 59 :96-103

[8]

HAMMETT LP, 1940, PHYSICAL ORGANIC CHE

[9] SPONTANEOUS ALTERNATING CO-POLYMERIZATION OF TETRACYANOQUINODIMETHANE WITH STYRENE [J].

IWATSUKI, S ;

ITOH, T ;

HORIUCHI, K .

MACROMOLECULES, 1978, 11 (03) :497-500

[10] PREPARATION AND POLYMERIZATION OF ALPHA,ALPHA,ALPHA',ALPHA',2,5-HEXACHLORO-PARA-XYLYLENE [J].

IWATSUKI, S ;

KAMIYA, H .

MACROMOLECULES, 1974, 7 (06) :732-737

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