NEW POLYMER ELECTROLYTE SYSTEMS

被引：10

作者：

COWIE, JMG

ANDERSON, AT

ANDREI, M

MARTIN, ACS

ROBERTS, C

机构：

[1] Department of Chemistry, Heriot-Watt University, Edinburgh

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 09期

关键词：

ION CONDUCTION; COMB-BRANCH POLYMERS; AZA-MACROCYCLES; DIVALENT CATION SALTS; POLYMER ELECTROLYTES;

D O I：

10.1016/0013-4686(92)80107-W

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Conductivities in a number of polymer electrolyte systems have been investigated using divalent cation salts such as Mg(ClO4)2, Ca(ClO4)2, Ni(ClO4)2 and ZnCl2. The polymers used were comb-branched structures with oligo(ethylene oxide) and oligo(propylene oxide) side chains and polyphosphazene networks linked by tetra-aza-macrocycles. The systems using Mg and Ca salts achieved levels as high as 10(-3)-10(-4) S cm-1 but the aza-macrocycles were about two orders of magnitude poorer.

引用

页码：1539 / 1544

页数：6

共 15 条

[1] THIN-FILM SOLID-STATE POLYMER ELECTROLYTES CONTAINING SILVER, COPPER AND ZINC IONS AS CHARGE-CARRIERS [J].