UNSYMMETRICALLY DISUBSTITUTED FERROCENES .6. SYNTHESIS AND REACTIVITY OF SOME 2-SUBSTITUTED FERROCENEMETHANOLS AND -CARBOXALDEHYDES

被引：24

作者：

MARR, G

ROCKETT, BW

RUSHWORT.A

机构：

[1] Department of Applied Science, Wolverhampton College of Technology, Wolverhampton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 16卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81644-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of lithiated [(dimethylamino)methyl]ferrocene with paraformaldehyde and dimethylformamide has given 2-[(dimethylamino)methyl]ferrocenemethanol and 2-[(dimethylamino)methyl]ferrocenecarboxaldehyde, respectively. These aminoferrocenes have been converted into a variety of 1,2-disubstituted ferrocenes. 2-[(Dimethylamino)methyl](methoxymethyl)ferrocene has been reacted with lithium to yield the corresponding (lithiomethyl)ferrocene which was condensed with benzophenone. © 1969.

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页码：141 / &

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