DEOXYGENATION OF ALCOHOLS BY THE REACTIONS OF THEIR XANTHATE ESTERS WITH TRIETHYLSILANE - AN ALTERNATIVE TO TRIBUTYLTIN HYDRIDE IN THE BARTON-MCCOMBIE REACTION

被引：46

作者：

KIRWAN, JN ^{[1
]}

ROBERTS, BP ^{[1
]}

WILLIS, CR ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)97814-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

O-Alkyl S-methyl dithiocarbonates derived from primary or secondary alcohols (ROH) react with trialkylsilanes in non-aromatic solvents to give the corresponding hydrocarbons RH in good yields; the reductions are promoted by thiols which act as polarity reversal catalysts. © 1990.

引用

页码：5093 / 5096

页数：4

共 20 条

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