CIDEP DURING THE PHOTOLYSIS OF DI-TERT.BUTYL KETONE

被引：38

作者：

CARMICHAEL, I

PAUL, H

机构：

[1] Radiation Laboratory2 2 The research described herein was supported by the Office of Basic Energy Sc, the Department of Energy. This is Document No. 2044 from the Notre Dame Radiation Laboratory., University of Notre Dame, Notre Dame

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 67卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(79)85218-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The CIDEP of tert.butyl radicals during photolysis of di-tert.butyl ketone is analysed. Triplet and radical pair mechanism induce enhanced absorption and an E/A multiplet effect at the initiation stage. The F-pair polarization reflects S-To and S-T+ mixing due to a solvent dependent indirect exchange interaction with J > 0. © 1979.

引用

页码：519 / 523

页数：5

共 18 条

[1] ELECTRON-SPIN POLARIZATION DURING PHOTOLYSIS OF PIVALOPHENONE (PHENYL TERT-BUTYL KETONE) [J].