METHANE ACTIVATION BY AN IRON PHOSPHINE COMPLEX IN LIQUID XENON SOLUTION

被引：40

作者：

FIELD, LD

GEORGE, AV

MESSERLE, BA

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期

关键词：

D O I：

10.1039/c39910001339

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Irradiation of FeH2(dmpe)2 [dmpe = 1,2-bis(dimethylphosphino)ethane] in a solution of methane in liquefied xenon at -100-degrees-C affords a mixture of cis-FeH(dmpe)2Me and trans-FeH(dmpe)2Me; the cis and trans isomers equilibrate photochemically at -100-degrees-C but decompose thermally with elimination of methane at temperatures above ca. 0-degrees-C following solvent exchange with toluene.

引用

页码：1339 / 1341

页数：3

共 41 条

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