NEW ASPECTS ON THE PHOTOINITIATED FREE-RADICAL PROMOTED CATIONIC POLYMERIZATION

被引：80

作者：

YAGCI, Y

SCHNABEL, W

机构：

[1] Istanbul Technical University, Department of Chemistry, Maslak, Istanbul

[2] Hahn-Meitner-Institute, Berlin, 1000

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 60卷

关键词：

D O I：

10.1002/masy.19920600112

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

General aspects of the photoinitiated free radical promoted cationic polymerization are discussed. The applicability of pyridinium salts, a new class of photoinitiators, of appropriate redox potential E(red)1/2 in oxidizing carbon-centered free radicals to carbocations capable of initiating the polymerization of various compounds is demonstrated. Moreover, the use of polysilanes as source for readily oxidizable free radicals is described. Furthermore, possibilities for preparing block copolymers by free radical promoted cationic polymerization are pointed out.

引用

页码：133 / 143

页数：11

共 23 条

[1]

ALLEN NS, 1989, PHOTOPOLYMERIZATION

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