THE STEREOCHEMISTRY OF CARBONYL OXIDES FROM OZONOLYSIS OF VINYL ETHERS

被引：5

作者：

BUNNELLE, WH

LEE, SG

机构：

[1] Department of Chemistry University of Missouri, Columbia

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 44期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(94)88265-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The geometries of the carbonyl oxides produced during ozonolysis of E- and Z-vinyl ethers have been assigned using the intramolecular trapping method. The alkoxy substituent exerts an anti-directive effect on formation of the carbonyl oxide; that is, the carbonyl oxide has a geometry opposite to that of the precursor vinyl ether.

引用

页码：8141 / 8144

页数：4

共 6 条

[1] THE 1ST DETERMINATION OF CARBONYL OXIDE GEOMETRY - EFFECT OF RING SIZE ON THE STEREOCHEMISTRY OF CARBONYL OXIDES FROM OZONOLYSIS OF CYCLOALKENES [J].